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Knowledge

NACE MR0175 / ISO 15156 for buyers

NACE MR0175 / ISO 15156 limits materials and hardness for H2S service to prevent cracking. Learn the three parts, 22 HRC and what a buyer must specify.

6 min read

Updated

In short

NACE MR0175 / ISO 15156 is the standard for selecting metallic materials that resist cracking in oil and gas production environments containing hydrogen sulfide (H2S). Part 1 gives general principles, Part 2 covers carbon and low-alloy steels, and Part 3 covers corrosion-resistant alloys. The equipment user must define the environment; the manufacturer must supply material that meets the standard, and the buyer should ask for a written compliance statement.

Stud bolt with two heavy hex nuts
Fig. 01Stud bolt with two heavy hex nutsASTM A193 B7 · A194 2H · 3/4-10 UNC

What are NACE MR0175 and ISO 15156?

NACE MR0175 / ISO 15156
The joint standard, "Petroleum and natural gas industries: materials for use in H2S-containing environments in oil and gas production". It sets requirements and recommendations for selecting and qualifying metals that resist cracking caused by H2S.

The text is published by ISO as ISO 15156 and by NACE as NACE MR0175. NACE International is now part of AMPP, the Association for Materials Protection and Performance, which keeps the NACE standard numbers. The 2020 edition of the three parts was current when this guide was written, and a revision was in development. Name the edition on the purchase order.

The three parts of ISO 15156
PartTitleCovers
Part 1General principles for selection of cracking-resistant materialsScope, definitions, user and manufacturer responsibilities, cracking mechanisms, general rules
Part 2Cracking-resistant carbon and low-alloy steels, and the use of cast ironsSteel pipe, flanges, forgings, bolting, valve bodies, vessels, with hardness and heat treatment rules
Part 3Cracking-resistant CRAs and other alloysStainless steels, nickel alloys and other corrosion-resistant alloys, with limits by environment

What is sour service, and who decides?

Sour service is service in which water and H2S are present at levels that can crack susceptible materials. Cracking needs three things together: a susceptible material, tensile stress, and a wet environment with H2S.

ISO 15156-2 uses the H2S partial pressure and the in-situ pH to define severity regions for sulfide stress cracking of carbon and low-alloy steels. A partial pressure of 0.3 kPa (0.05 psi) is the commonly cited lower boundary of the sulfide stress cracking regions, with less demanding rules below it. The standard sets the exact rules, so read the clauses and not a summary.

The standard assigns the decision to the user of the equipment. The user, not the supplier, determines the process conditions: H2S partial pressure, pH, chlorides, temperature and total pressure. A distributor cannot know your fluid, so the order should state the conditions or say that the item must comply with the standard.

What kinds of cracking does it address?

Cracking mechanisms in H2S service
MechanismWhat happensTypical test or control
SSC, sulfide stress crackingBrittle cracking of hard steel under tensile stress in wet H2SHardness limits; laboratory testing to NACE TM0177
HIC, hydrogen-induced crackingPlanar cracks form inside plate or pipe steel from absorbed hydrogen, without applied stressClean steel; testing to NACE TM0284
SOHIC, stress-oriented HICStacked HIC cracks linked by stressMaterial quality, weld and heat treatment control
SCC, stress corrosion crackingCracking of corrosion-resistant alloys from stress, chlorides and H2SEnvironmental limits in Part 3

Summary only. ISO 15156 defines each mechanism and the controls that apply.

NACE TM0177 tests a metal specimen under stress in an H2S solution to see if it cracks. NACE TM0284 tests plate and pipe steels for HIC. These are laboratory methods. Whether a test is required comes from the standard, the owner's specification or a product standard such as API 5L Annex H, not from the test method itself.

What hardness limits are cited for carbon steel?

For carbon and low-alloy steels, the best-known limit is a maximum hardness of 22 HRC (Rockwell C) for the parent metal, where the hardness route is used. Hardness is a proxy for susceptibility: harder steel cracks more readily in H2S.

That figure is a summary, not the full rule. The standard sets how hardness is measured and where, separate limits for welds and heat-affected zones, the need for post-weld heat treatment, exceptions and alternative qualification routes. ISO 15156-2 is the authority, and the edition on the order governs.

Bolting shows why this matters. ASTM A193 B7 studs can be harder than sour service limits allow. Specifiers choose A193 B7M studs with A194 2HM nuts, which are produced to a controlled maximum hardness. See Stud bolts and gaskets.

What is the buyer's role?

Who does what
PartyResponsibility
Equipment user or purchaserDefines the environment, names the standard and edition, and states sour service on the order
ManufacturerSelects and produces material that meets the standard, controls heat treatment, tests hardness and issues the records
Distributor or sourcing agentPasses on the order requirements and the manufacturer's documents, and keeps heat traceability
InspectorWitnesses tests or reviews records when the order requires it
  • Name the standard and edition: for example ISO 15156-2 or NACE MR0175 / ISO 15156, edition year.
  • Give the service conditions, or state that the item must meet the standard without further limits.
  • Cover every wetted and pressure-boundary part: pipe, flanges, fittings, valves, bolting and gaskets metal parts.
  • Require a compliance statement from the manufacturer, and the hardness results, heat treatment and heat number on an EN 10204 type 3.1 or 3.2 certificate.
  • Name a third-party inspector for 3.2 when the owner requires it.

See Material test reports for how to check the certificate against the order.

How can JJ Projects help?

JJ Projects does not certify materials to NACE MR0175 / ISO 15156. It sources items to the specifications you name, requests the manufacturer's compliance statement and test records, and checks them against your purchase order. State sour service in your Request a quote, or see steel and structural products.

Stud bolt with two heavy hex nuts
Fig. 01Stud bolt with two heavy hex nutsASTM A193 B7 · A194 2H · 3/4-10 UNC
Weld neck flange
Fig. 02Weld neck flangeASME B16.5 · WN · RF · CL 150

Sources

  1. ISO 15156-1:2020, Materials for use in H2S-containing environments in oil and gas production, Part 1: general principles
  2. ISO 15156-2, Cracking-resistant carbon and low-alloy steels, and the use of cast irons
  3. ISO 15156-3, Cracking-resistant CRAs (corrosion-resistant alloys) and other alloys
  4. AMPP (formerly NACE International), standards catalogue: NACE MR0175/ISO 15156, TM0177, TM0284
  5. TWI, NACE TM0177 sour test methods
  6. Texas Flange, NACE MR0175 flanges for sour service

Questions

Questions

01What is the difference between NACE MR0175 and ISO 15156?

They are the same technical text published under two names. MR0175 / ISO 15156 is the common reference and is now maintained with AMPP, the successor of NACE International.

02What is the difference between NACE MR0175 and MR0103?

MR0175 / ISO 15156 is for oil and gas production. MR0103 is for sulfide stress cracking in refinery and downstream environments. Use the one your project specification names.

03Is 22 HRC the hardness limit for all materials?

No. It is the figure commonly cited for carbon and low-alloy steel parent metal. Welds, other alloys and other routes have their own rules. Check the standard.

04Does the whole assembly need to be NACE compliant, or only the flange?

Every pressure-containing and wetted component that the standard applies to: pipe, flange, fitting, valve, bolting and metal gasket parts. Specify it for each line item.

05Do I need an EN 10204 3.2 certificate for sour service?

Often owners ask for 3.1 or 3.2 with hardness results. Whether 3.2 is required is the owner's decision, so state it on the order.

06Can a distributor certify an item as NACE compliant?

A distributor can pass on the manufacturer's statement and records. The compliance rests on the material, its heat treatment and its test results at the manufacturer.

Send the specification. We will take it from there.

A material list, a drawing or a single line: tell us what the project needs and where it is going.